Ok, I'll take a crack at it:
1. Anyone can do the alignment, but in my experience it's very hard to find someone that does a good job. Most shops have people that don't really care about that last 1/2 degree or their alignment machine is hosed. Therefore, I do my alignment manually in my own garage using turntables, castor/camber gauge, tape measures and string.
2. Hmmm, there is something very bad about mixing these coolants. If I remember right the chemical reaction causes sludge. You need to do a complete flush, get it all out.
http://www.getahelmet.com/jeeps/maint/dexcool
3. Go with AC or NGK platinum, stay away from Bosch.
4. Pretty standard, same as any other vehicle. Don't forget to use friction additive in your rear-end. Redline make excellent oil for the rear-end.
5. Nothing goes in my gas tank except for gas and fuel stabilizer in the winter. Your engine runs hot and efficient enough that carbon build up is not a problem.
6. Brake pads...you get what you pay for. You can't go wrong with the factory pads. Performance Friction are good quality pads as well but expensive. BTW, the service manual states only turn the rotors if they are warped (vibration under braking) or they have grooves deeper than 2mm if I remember right.
7. Always use Mobile 1 oil and don't forget to wave when you meet another Vette!!
Have fun!